Decommissioning, Immobilisation and Storage
soluTIons for NuClear wasTe InVEntories

Legacy Ponds and Silo Wastes

DISTINCTIVE is a multi-disciplinary collaboration of 10 universities and 3 key industry partners from across the UK’s civil nuclear sector. 

One step extraction and quantification of radionuclides using superparamagnetic bead and nanopore technologies

One step extraction and quantification of radionuclides using superparamagnetic bead and nanopore technologies

PhD/PDRA – PhD

Academic Lead – Mark Platt

Researcher – Laura Mayne

University – Loughborough University

Loughborough University has developed a range of polymeric ligands with the capacity to selectively bind trace radioactive contaminants from solutions containing abundant major cations1, e.g. Na+, Mg2+, Ca2+. These ligands will be immobilised onto silica-coated superparamagnetic beads which can be quickly removed from solution using a magnetic field. We have the ability to synthesise beads of uniform sizes and magnetic properties2,3, which allows us to match a bead size with a specific contaminant, e.g. 0.5 µm with a ligand that binds to radionuclide 1 and a 0.55 µm bead with a ligand that binds to radionuclide 2. During the extraction, the different sized beads can be separated from each other allowing simultaneous separation of target species by magnetophoresis4. The amount of radionuclides bound to the surface ligands will be quantified using a nanopore technology, as the beads are passing through the nanopore, the change in surface charge and ligand structure caused by the presence of the radionuclide can be accurately measured5,6 and has recently been demonstrated with biological components using the same technology with ppb sensitivity7. Potential to remove trace contaminants from ponds and waste streams, without compromising waste management down-stream.

 

  1.  S. Christie S. Edmondson and N. Evans NDA funded studentship – work presented at NDA PhD seminar, Manchester, Jan 2013.
  2. M. Platt, et. al.” Microparticles and a device and method for the synthesis of microparticles” U02-759-03GB
  3. J. O’Mahony, D. Kilinc, M. Platt, G. Lee, Langmuir, (2013) 29, 2546
  4.  N. Pamme, Lab Chip, (2006) 6, 24
  5. M. Platt, et. al Small, (2012) 8, 2436
  6. M. Platt, et. al Biomicrofluidicis, (2012) 6, 01410
  7. M. Platt et. al Article Submitted

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